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Hydrogen Production by Homogeneous Partial Oxidation of Propane

Identifieur interne : 000951 ( Main/Exploration ); précédent : 000950; suivant : 000952

Hydrogen Production by Homogeneous Partial Oxidation of Propane

Auteurs : Céline Hognon [France] ; Yves Simon [France] ; Paul-Marie Marquaire [France]

Source :

RBID : Pascal:12-0189766

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English descriptors

Abstract

A kinetic study of the partial oxidation of propane was performed in a jet stirred reactor. The main goal of this study was to establish a detailed homogeneous mechanism of this reaction and explore the capability to produce H2 and olefins. Various operating parameters are modified: temperature, residence time, and O2/C3H8 ratio. The mechanism was validated by comparing experimental and simulated results. A different behavior was observed depending on the temperature. At 600 °C, the mechanism contains both an oxidation and a pyrolytic path. The main products are H2, C2H4, CH4, CO, and O2. At 800 °C, the mechanism mostly contains a pyrolytic path. The main products are H2 and CO.

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Le document en format XML

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<term>Homogeneous reaction</term>
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<term>Propane</term>
<term>Reaction mechanism</term>
<term>Residence time</term>
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<term>Production hydrogène</term>
<term>Oxydation partielle</term>
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<term>Réaction homogène</term>
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<div type="abstract" xml:lang="en">A kinetic study of the partial oxidation of propane was performed in a jet stirred reactor. The main goal of this study was to establish a detailed homogeneous mechanism of this reaction and explore the capability to produce H
<sub>2</sub>
and olefins. Various operating parameters are modified: temperature, residence time, and O
<sub>2</sub>
/C
<sub>3</sub>
H
<sub>8</sub>
ratio. The mechanism was validated by comparing experimental and simulated results. A different behavior was observed depending on the temperature. At 600 °C, the mechanism contains both an oxidation and a pyrolytic path. The main products are H
<sub>2</sub>
, C
<sub>2</sub>
H
<sub>4</sub>
, CH
<sub>4</sub>
, CO, and O
<sub>2</sub>
. At 800 °C, the mechanism mostly contains a pyrolytic path. The main products are H
<sub>2</sub>
and CO.</div>
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